Chloe

Chloe is Amy Jordan's biggest rival and enemy who has sex with James Kendrick in Pilot. It is implied by James as they are having sex that they have sex often, meaning they were in an active sexual affair. However, James later breaks things off with Chloe after Amy realizes he's been cheating.

Pilot
Chloe is seen having sex with James Kendrick after he fails to have sex with Amy Jordan. It is implied that they've had sex before and it is also known that Chloe is Amy's biggest enemy.

Personality
Since Chloe is having a sexual affair with James it is shown that she may not be the best person around with the best morals. She is also described by Amy as being a "superbitch".

James Kendrick
Chloe has sex with James in Pilot despite James being in a relationship with Amy, and James implies that this is not the first time they've had sex together.

Amy Jordan
Amy views Chloe as being her biggest enemy and rival, and calls chloe a "superbitch".

Season 1

 * Pilot (debut episode)
 * Garage

Trivia

 * She is the first non-main character introduced, and the first character introduced who isn't a member of the gang.